ASPARTIC ACID
ASP, D

CHEMICAL STRUCTURE
CHEMICAL SHIFTS
Standard chemical shifts of random extended chain structures:
 
1Ha 13Ca 15Nb
NH: 8.41 
HA: 4.76
HB: 1.84, 1,75
CO: 174.2 
CA: 52.7
CB: 39.8
CG: 178.4
N: 120.6
a) from 86BOOK1: b) from 91JMB311-222
More info in:
  • 1H chemical shifts of amino acids
  • 13C chemical shifts of amino acids
  • Average 1HA, 1HN and 15N chemical shifts in random coil
  • IDENTIFICATION
    Easy spin system identification from:
    SECONDARY STRUCTURE
    Standard average chemical shift values used in determination of secondary structure by means of the CSI method:
    HA: 4.76
    CA: 53.9
    CO: 176.8
    Thus:

              HELIX           B STRAND          COIL
                 CA      CO       CA      CO           CA      CO
                56.7    177.9     52.3    176.0      54.2    176.8

    More info in: 13CA and 13CO chemical shifts according to secondary structure.

    OBSERVATIONS
     
    RELATED TOPICS