RDC in small molecules
Use of Residual Dipolar Couplings (RDCs) in small molecules:
  • Recommended Reading: ( 05MRC53)
  • RDCs in carbohydrates
  • Determination of stereochemistry in six-membered chairlike rings ( 03JOC1786)
  • Measurement of direct and long-range proton-carbon and carbon-carbon RDCs in oriented media taking the menthol as an example ( 03JMR353-163)
  • Analysis of relative stereochemistry of multiple stereocenters ( 03CC154 and 04JACS5008)
  • Diastereotopicity of methylene protons ( 03OL705 and 04JMR307-168)
  • Conformational analysis of
  • alanine dipeptide ( 03JPCB3265) and observation of RDCs in short peptides ( 03SFG546)
  • two lipophilic cannabinoids ( 03JMC4838)
    • Anisotropic media for small molecules:
  • poly-g-benzyl-L-glutamate (PBLG) in CDCl3
  • poly-g-ethyl-L-glutamate (PELG) in CDCl3 ( 04JOC7403)
  • Strain-induced alignment in a gel (SAG)
  • Stretched poly(dimethylsiloxane) gels ( 04JACS14690)
  • In aqueous solution: Mechanically strectched polyacrylamide or acrylamide/acrylate copolymer
  • Cross-linked polystyrene (PS) ( 04ANG1092)
  • DMSO compatible orienting medium: copolymeric cross-linked polyacrylamide (PH gel) ( 05ANG427)
  • Stretched poly(vinyl acetate) (PVAC) gels compatible in polar organic solvents ( 05ANG423)
  • Use of deuterated liquid solvent such as PCBP (4-n-pentyl-4'-cyanobiphenyl-d19) ( 02JACS14862)
  • Chiral ALignment media for the discrimination of enantiomers:
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