NMR in Chemistry

Chiral Alignment media for the discrimination of enantiomers by NMR:
  • General review: ( 02ENC497)
  • Use of 2H-NMR in polypeptide liquid crytals ( 02OL1663 , 00CC2069 , 02JMR169-158 , 03CEJ1724 , 03CEJ4536 , 03JACS7689 , 04MRC594 and 04AC2827 )
  • Use of quiral poly-g-benzyl-L-glutamate (PBLG) in CDCl3 ( 05MRC512). Measurement of D(HH) and D(CH) using a F2-coupled HSQC experiment.
  • Use of stretched gelatin gels ( 05ANG2). Measurement of J(CH) from a F1-coupled HSQC experiments using a BIRD cluster inside t1 to remove long-range J(CH) interactions.
  • Also see Measurement of Residual Dipolar COuplings in small molecules
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