Saccharide NMR

  • Revision works on:
  • Carbohydrate NMR and modeling: ( 96COP710 , 96COP659 , 95COP591 )
  • Carbohydrate-carbohydrate interactions ( 95JACS11198 )
  • Complex carbohydrates of glycoproteins and glycolipids ( 99ARB269 and 02CR371 )
  • Free and protein-bound carbohydrates ( 99COP549 ). Also see Carbohydrate-protein complexes
  • Spectral simplification by O-acetylation. Location of acetylation via 3JHCOC (2.5-4.7 Hz)
  • 1H and 13C NMR of aldopyranose and aldofuranose monosaccharides ( 96MRC755 ). Study of acycloc forms in 1-13C labeled aldohexoses from 13C NMR and deuterium isotope effects ( 01JOC6244 ).
  • Hydroxymethyl conformation ( 01JACS4781 and 02JOC949 )
  • Structural studies on nitrogen-containing saccharides ( 99JPC3783 and 00JACS6435 )
  • Determination of acid dissociation constants of amino sugars ( 97CRS163-298 )
  • NMR of C-glycosides ( 88MRC1062 , 94JOC6629 , 96ANG303 )
  • Diffusion studies on sugars
  • CSA of anomeric protons ( 93MRC665 )
  • Saccharides from natural sources:
  • Tri- and tetrasaccharides from asparagus ( 00MRC1005 )
  • Heptasaccharide from Streptococcus sanguis J22 ( 90BIO234 )
  • NMR examples:
  • Sucrose Octaacetate ( 86MRC179 )
  • Gentiobiose octaacetate ( 89MRC223 )
  • Conformational properties of sucrose ( 91JACS3720 )
  • Cellobiose ( 80JACS1745 )
  • Sialosides ( 94JACS1616 )
  • 13C isotopic enrichment for NMR studies of carbohydrates and glycoconjugates ( 01METH305 ) 90PROG55