NMR Experiments

  • NOESY and TOCSY experiments recorded with short mixing times, fast relaxation delays, and short acquisition times are usually employed to identify spin systems in close proximity to the paramagnetic center.
  • Super-WEFT experiment ( 83JMR128-51 ) allows the observation of resonances with fast R1 relaxation rates while suppressing the slowly relaxing signals. Advantages: fewer resonances, better spectral resolution and improved sensitivity due to the fast repetition rate. Application to the measurement of electron self-exchange rates ( 01JB199-19 )
  • Aspects of COSY spectra of paramagnetic macromolecules ( 94CONC307 )
  • Tailored HCCH-TOCSY for paramagnetic complexes ( 02JMR236-155 )
  • 2D & 3D Carbon-detected NMR Experiments
  • 1D Stopped-flow NMR for studying the kinetics of metal exchange in biomolecular systems ( 02JB303 )

    Other NMR methodology described in:

  • 93JMRB309-101
  • 94JMRB230-104
  • 93METH1
  • 94METH485
  • 95JB202-5
  • 96JMRB88-113
  • 96JB171-8
  • 97JACS12643
  • 97JB299-9
  • 98JMR154-134
  • 98JB509-12
  • 98ICA373
  • 99JACS11575