DESCRIPTION
The half-gaussian shape was presented as a useful alternative
to gaussian shape because does not create significant amounts of antiphase
magnetization, but leads almost quantitatively to in-phase magnetization
of the selected signal.
REQUIREMENTS
The half-gaussian shape can be generated in the SHAPE
tool.
VERSIONS
Half-gaussian shapes pulses were originally proposed to achieve
selective excitation of single multiplet lines (
87JMR390-75
). However,
while the absorptive part of the excitation profile shows an excellent
selectivity, its dispersive mode component has a unacceptably large band
width that must be removed. This is usually achieved by applying a non-selective
90y,-y degree pulse immediately after the half-gaussian pulse.
Application in selective 1D and 2D experiments requiring in-phase components
was reported (
89JMR1-85
).
EXPERIMENTAL DETAILS
More details in Tutorials:
Defining a Half-gaussian shape.
PROFILE
The theoretical excitation profile of a half-gaussian
shaped 90 degree pulse can be visualized from the NMRSIM
program:
-
Select the corresponding File-->Experiment Setup-->Load from File
... menu.
-
Choose the profile.cfg configuration file.
-
Set the shape to hgauss3.shp in the
Go-->Check Experiment parameters menu.
-
Select the Go-->Run Experiment menu.
-
The result of the simulation is displayed in the nmrsim 1 1 file
into the XWIN-NMR window. Transform the data with ef (lb=1).
-
The duration of the shaped pulse can be modified by changing the P5
parameter (by default, 5 ms) in
the Go-->Check Experiment parameters menu. Repeat the 4 and
5 steps to obtain the new profile.
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