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In heteronuclear experiments, a single refocusing pulse is often used to remove the effects of the heteronuclear coupling over a period. Thus, if a PFG is applied in the opposite sense, any coherences on I-spin will be rephased whereas the 180° pulse on S acts as a simple inversion pulse. The net effect is that the chemical shift of I-spin freely evolves during the overall duration of the two PFGs but the heteronuclear coupling is refocused.REQUIREMENTSSee some examples:
Easy implementation on AVANCE spectrometers equipped with gradient technology.EXPERIMENTAL DETAILS
SYNTAX
The standard way to implement a heteronuclear decoupling element in a pulse program is:RELATED TOPICSin which:
...
d13
p16:gp1
d16
(p4 ph1):f2
d13
p16:gp2
d16
...
- p4 is the high-power 180 degree pulse from the f2 decoupler channel.
- p16 is the duration of the gradient (in microseconds)
- d16 is the recovery time (in seconds) needed after the gradient
- gp1 and gp2 stand for the gradient strength defined in the gpz1 and gpz2 commands, where gpz1=-gpz2. Otherwhise, gpnam1 and gpnam2 define the shape of the gradients.