Heteronuclear Decoupling
(using gradients)

DESCRIPTION
 In heteronuclear experiments, a single refocusing pulse is often used to remove the effects of the heteronuclear coupling over a period. Thus, if a PFG is applied in the opposite sense, any coherences on I-spin will be rephased whereas the 180° pulse on S acts as a simple inversion pulse. The net effect is that the chemical shift of I-spin freely evolves during the overall duration of the two PFGs but the heteronuclear coupling is refocused.

See some examples:
 

REQUIREMENTS
Easy implementation on AVANCE spectrometers equipped with gradient technology.
EXPERIMENTAL DETAILS
 
SYNTAX
The standard way to implement a heteronuclear decoupling element in a pulse program is:
...
d13
p16:gp1
d16
(p4 ph1):f2
d13
p16:gp2
d16
...
in which:
RELATED TOPICS
 
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