|
A constant-time (CT) period involve one spin undergoing chemical shift evolution while simultaneously building up or refocusing antiphase coherence with other spins. Thus, during a CT period of lenght 2T (or 2*d5), chemical shift of the selected X spin evolves only during a variable t1 period whereas homonuclear couplings, JXX, only evolves during the fixed 2*d5 period (see general scheme for CT period in a two-spin system (IX) ).
On the other hand, in a three-spin system, IXY, in which :several schemes can be clearly designed as a function of the evolution of the corresponding JIX and JXY coupling constants into the Ct period:
- X undergo chemical shift evolution.
- JIX>JXY>0 and JIY=0
- I is always a heteronuclear spin with respect X and Y (they can be homo- or heteronuclear spins).
Case A: No J coupling evolution Case B: Case C Case D: Evolution of both coupling constants JIX 0 0 0 2*d6 JXY 0 2*d5 2*d4 2*d4 JXX' 2*d5 2*d5 2*d5 2*d5