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Zirconium NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
91Zr
11.22
5/2
-2.49743
-0.176
46.651
9.48*10-3
1.06*10-3
 

APPLICATION FIELDS

 
NMR REFERENCES
A saturated solution of Zr(C5H5)Cl2 in CH2Cl2 is used as an external reference sample (absolute frequency of 9,296298 MHz with respect to 100.00 MHz of TMS). Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
 Some interesting features of the Zr nucleus are:
NMR EXPERIMENTS
 1D 91Zr spectrum
BIBLIOGRAPHY
 Revision work: B91PRE1
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