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Titanium NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
47Ti
7.44
5/2
-1.5105
0.29
28.184
2.09*10-3
1.52*10-4
49Ti
5.41
7/2
-1.51095
0.24
28.191
3.76*10-3
2.07*10-4
 

APPLICATION FIELDS

 
NMR REFERENCES
TiCl4 neat is used as a standard reference sample. Its absolute frequency is 5.637534 MHz for 47Ti and 5.639037 MHz for 49Ti with respect to 100.00 MHz of TMS. Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
 47Ti/49Ti chemical shifts
NMR EXPERIMENTS
 1D 47Ti/49Ti spectrum
BIBLIOGRAPHY
Revision work: B91PRE1.
The Transition Metals NMR: B79HAR195, 00ENC730 .
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