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Scandium NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
45Sc
100
7/2
6.5087973
-0.22
121.47
0.3
0.3
 

APPLICATION FIELDS

45Sc NMR spectroscopy has been applied on inorganic compounds and organoscandium complexes.
NMR REFERENCES
A salt of Sc3+ (Sc(NO3)3) in D2O is used as a standard reference sample. Its absolute frequency is 24.291747 MHz with respect to 100.00 MHz of TMS. Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
 Some interesting features of the Sc nucleus are:
NMR EXPERIMENTS
 1D 45Sc spectrum
BIBLIOGRAPHY
Revision work: B91PRE1.
The Transition Metals NMR: B79HAR195, 00ENC730 .
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