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Platinum NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance 
frequency
(MHz)
at 11.744T
(500 MHz for protons)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
195Pt
33.832
1/2
 5.8385
0
107.495
9.94*10-3
3.36*10-3
 
APPLICATION FIELDS
195Pt NMR spectroscopy is applied on iInorganic and organometallic platinum-containing compounds. Some solid-state application have also been reported.
NMR REFERENCES
A commonly used external reference is 1.2M Na2PtCl6 in D2O ( absolute frequency of 21.496784 MHzwith respect to the 100.00 MHz of TMS). Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
Some interesting features of the Pt nucleus are:
NMR EXPERIMENTS
In platinum-containing compounds the following experiments can be helpful:
BIBLIOGRAPHY
 Interesting review: B91PRE216, 00ENC718 .
The Transition Metals NMR: B79HAR195.
195Pt NMR in homo- and heteronuclear clusters ( B96GIE313).

93IC5206
93IC2049
93IC2717
92JOC225-435
92MRC481
92MRC697
91IC4328
90DALTON3335
90JACS6860
90MRC99
90CC1121
86IC974

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