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Nickel NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
61Ni
1.1399
3/2
-2.3948
0.162
44.681
3.57*10-3
4.25*10-5
 

APPLICATION FIELDS

 61Ni NMR spectroscopy is applied on inorganic and organometallic nickel-containing compounds although is extremely difficult to observe due to the presence of very broad signals.
NMR REFERENCES
NI(CO)4 is used as an external reference sample (absolute frequency of 8.936051 MHz with respect to 100.00 MHz of TMS). Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
Some interesting features of the Ni nucleus are:
NMR EXPERIMENTS
1D 61Ni spectrum
2D 31P-61Ni correlation experiment using phosphorus detection ( 88MRC895 ).
BIBLIOGRAPHY
  Interesting review: B91PRE216, 00ENC730
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