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Lanthanum NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
 138La
0.090 
3.557239
0.45
 65.965
9.19*10-2 
8.18*10-5 
139La
99.91
7/2
3.8083318
0.20
70.631
5.92*10-2
5.91*10-2
 

APPLICATION FIELDS

 139La NMR spectroscopy has been applied on inorganic and organolanthanum compounds.
NMR REFERENCES
An aqueous sample of 0.01M LaCl3 is recommended as a standard. The absolute frequency is 14.125641 MHz with respect to 100.00 MHz of the TMS signal. Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
 139La chemical shifts
Long T1 values
NMR EXPERIMENTS
 1D 139La spectrum
BIBLIOGRAPHY
 Revision work: B91PRE1
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