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Arsenic NMR

PHYSICAL PROPERTIES
 

Isotope
Natural 
Abundance
(%)
Nuclear
Spin
(I)
Magnetogyric
ratio
(107*rad/T*s)
Quadruple 
moment
(1028*Q/m2)
Resonance
frequency
(MHz)
at 11.744T
(500 MHz for 1H)
Relative 
sensitivity
(1H=1.00)
Absolute 
sensitivity
(1H=1.00)
75As
100
3/2
4.596163
0.314
85.634
2.51*10-2
2.51*10-2
 

APPLICATION FIELDS

 
NMR REFERENCES
0.5M NaAsF6 in CD3CN is used as an external standard reference. Its absolute frequency is 17.122614 MHz with respect to 100.00 MHz of the TMS signal. Also see IUPAC recommendations for reporting the NMR chemical shits of all nuclei relative to the 1H resonance of TMS (02JMR323-156).
NMR PARAMETERS
 75As chemical shift
NMR EXPERIMENTS
 1D 75As spectrum
BIBLIOGRAPHY
Revision work: B79HAR379, 00ENC685 .
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